Metal Catalysts and Ligands
for Organic Synthesis
Listed below are the new Metal Catalysts and Ligands for Organic Synthesis introduced in Catalog 18. For a complete listing see the "blue section" of our catalog please email to sales@advtechind.com
Flagged items have been introduced since Catalog 18 was printed.
ALUMINUM
13-5800 (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum (III) chloride, 98% 1g
5g
13-5801 (1S,2S)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum (III) chloride, 98% 1g
5g
CHROMIUM
24-0850 (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]chromium (III) chloride, 98% 1g
5g
24-0851 (1S,2S)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]chromium (III) chloride, 98% 1g
5g
COBALT
27-0525 (1R,2R)-(-)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-
butylsalicylidene)cobalt (II)
 1g
5g
25g
27-0526 (1S,2S)-(+)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-
butylsalicylidene)cobalt (II)		 1g
5g
25g
COPPER
29-6700
 Tetrakis(acetonitrile)copper (I) hexafluorophosphate, 98+% 5g
25g
Technical Note:
  1. Useful catalyst for the Ullman synthesis.






Reference:
  1. J. Org. Chem., 1999, 64, 2986.
IRON
26-0200 (+)-1,1'-Bis((2R,4R)-2,4-diethylphosphotano)ferrocene, min. 95% (R,R)-Et-FerroTANEÔ
Note: Sold for research purposes only. Sold in collaboration with Chirotech.		 100mg
500mg
26-0201 (-)-1,1'-Bis((2S,4S)-2,4-diethylphosphotano)ferrocene, min. 95% (S,S)-Et-FerroTANEÔ

Note: Sold for research purposes only. Sold in collaboration with Chirotech.

 100mg
500mg
26-0275 1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98% 500mg
2g
LANTHANUM
57-0200 Di-[3-((R)-2,2'-dihydroxy-1,1'-binaphthylmethyl)]ether, lanthanum (III) salt SCT-(R)-BINOL
 100mg
500mg
57-0201 Di-[3-((S)-2,2'-dihydroxy-1,1'-binaphthylmethyl)]ether, lanthanum (III) salt SCT-(S)-BINOL 100mg
500mg
MOLYBDENUM
42-1212 2,6-Diisopropylphenylimidoneophylidene[racemic-BIPHEN]
molybdenum (VI), min. 97%
rac-SCHROCK-HOVEYDA CATALYST		 100mg
500mg
2g
BIPHEN=5,5',6,6'-Tetramethyl-3,3'-di-t-butyl-1,1'-biphenyl-2,2'-diol
42-1213 2,6-Diisopropylphenylimidoneophylidene[(R)-(+)-BIPHEN]
molybdenum (VI), min. 97%
(R) SCHROCK-HOVEYDA CATALYST		 100mg
500mg
2g
42-1214 2,6-Diisopropylphenylimidoneophylidene[(S)-(-)-BIPHEN]
molybdenum (VI), min. 97%
(S) SCHROCK-HOVEYDA CATALYST		 100mg
500mg
2g
NICKEL
28-0500 Dichloro[1,1'-Bis(diphenylphosphino)ferrocene]nickel (II) 1g
5g
NITROGEN
07-0299 1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride, min. 95%
 1g
5g
07-0302 1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium tetrafluoroborate
 1g
5g
07-0303 (+)-2,6-Bis[(4R)-4-phenyl-2-oxazolin-2-yl]pyridine, 98+%
 500mg
2g
07-0304 (-)-2,6-Bis[(4S)-4-phenyl-2-oxazolin-2-yl]pyridine, 98+% 500mg
2g
07-0340 (-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide), min. 98% 1g
5g
07-0341 (+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide), min. 98%
 1g
5g
07-0590 1,3-Bis(2,6-di-i-propylphenyl)imidazolium chloride, min. 95% 500mg
2g
OXYGEN
08-0600 (R)-(+)-3,3'-Dibromo-1,1'-bi-2-naphthol, 99%
 100mg
500mg
08-0601 (S)-(-)-3,3'-Dibromo-1,1'-bi-2-naphthol, 99% 100mg
500mg
08-0605 (R)-(+)-6,6'-Dibromo-1,1'-bi-2-naphthol, 99%
 500mg
2g
08-0606 (S)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol, 99% 500mg
2g
08-2045 racemic-5,5',6,6'-Tetramethyl-3,3'-di-t-butyl-1,1'-biphenyl-2,2'-diol, 99%
rac-BIPHEN H2
 5g
25g
08-2046 (R)-(+)-5,5',6,6'-Tetramethyl-3,3'-di-t-butyl-1,1'-
biphenyl-2,2'-diol, 99%
(R) BIPHEN H2		 100mg
500mg
2g
08-2047 (S)-(-)-5,5',6,6'-Tetramethyl-3,3'-di-t-butyl-1,1'-
biphenyl-2,2'-diol, 99%
(S) BIPHEN H2		 100mg
500mg
2g
PALLADIUM
46-0252 Bis(tri-t-butylphosphine)palladium (O), 98% 250mg
1g
46-0290 trans-Di(µ-acetato)bis[o-(di-o-tolylphosphino)benzyl]
dipalladium (II), 98+%
 1g
5g
PHOSPHORUS
15-0145 2,2'-Bis(diphenylphosphino)-1,1'-biphenyl, 98% BIPHEP
 250mg
1g
15-0425 (R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95% (R)-PHANEPHOS 100mg
500mg
15-0426 (S)-(+)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95% (S)-PHANEPHOS
 100mg
500mg
15-0380 Bis(2-diphenylphosphinophenyl)ether
 5g
25g
15-0410 (+)-1,2-Bis((2R,5R)-2,5-di-i-propylphospholano)benzene, 98+%
(R,R)-i-Pr-DUPHOS		 100mg
500mg
2g
15-0411 (-)-1,2-Bis((2S,5S)-2,5-di-i-propylphospholano)benzene, 98+%
(S,S)-i-Pr-DUPHOS		 100mg
500mg
2g
15-0960 (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis (2'-diphenylphosphinobenzoyl), 98%
TROST LIGAND

Note: Sold in collaboration with Chirotech.		 100mg
500mg
2g
15-0961 (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-
bis (2'-diphenylphosphinobenzoyl), 98%
TROST LIGAND
Note: Sold in collaboration with Chirotech.		 100mg
500mg
2g
15-0963 (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl, min. 94% TROST LIGAND (NAPHTHYL)
Note: Sold in collaboration with Chirotech.		 100mg
500mg
2g
15-0964 (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl, min. 94% TROST LIGAND (NAPHTHYL)

Note: Sold in collaboration with Chirotech.		 100mg
500mg
2g
15-1043 racemic-2-(Di-t-butylphosphino)-1,1'-binaphthyl, 98%
 250mg
1g
15-1045 2-(Di-t-butylphosphino)biphenyl, 99%
 500mg
2g
15-1140 2-(Dicyclohexylphosphino)biphenyl, 98%
 500mg
2g
15-1145 2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl, 98%
 500mg
2g
15-1148 2-(Dicyclohexylphosphino)-2'-methylbiphenyl, 99% 500mg
2g
15-1242 9,9-Dimethyl-4,5-bis(diphenylphosphino)xanthene, min. 98%
XANTPHOS
 1g
5g
15-1745 2-(Diphenylphosphino)-2'-(N,N-dimethylamino)biphenyl, 98% 500mg
2g
15-1773 (-)-(2S,4S)-2-Diphenylphosphinomethyl-4-diphenyl
phosphino-1-t-butoxycarbonylpyrrolidine BPPM
 100mg
500mg
15-1821 (R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole, 98%
 250mg
1g
15-1822 (S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole, 98% 250mg
1g
15-5811 Tri-t-butylphosphine, 99% (10 wt% in hexane) 1g
5g
15-5812 Tri-t-butylphosphine, 99% (10 wt% in hexane) (Sure/SealÔ bottle) 5g
15-7720 Tris(2,4-di-t-butylphenyl)phosphite, 98% 10g
250g
1kg
RHODIUM
45-0148 (-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene
(cyclooctadiene)rhodium (I) tetrafluoroborate, 98+%
(R,R)-Et-DUPHOS-Rh		 100mg
500mg
2g
45-0149 (+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene
(cyclooctadiene)rhodium (I) tetrafluoroborate, 98+%
(S,S)-Et-DUPHOS-Rh		 100mg
500mg
2g
45-0154 (+)-1,1'-Bis((2R,4R)-2,4-diethylphosphotano)ferrocene(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate, min. 98%

Note: Sold for research purposes only. Sold in collaboration with Chirotech.

 100mg
500mg
45-0155 (-)-1,1'-Bis((2S,4S)-2,4-diethylphosphotano)ferrocene(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate, min. 98%

Note: Sold for research purposes only. Sold in collaboration with Chirotech.

 100mg
500mg
45-0158 (-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene
(cyclooctadiene)rhodium (I) tetrafluoroborate, 98+%
(R,R)-Me-DUPHOS-Rh		 100mg
500mg
2g
45-0159 (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene
(cyclooctadiene)rhodium (I) tetrafluoroborate, 98+%
(S,S)-Me-DUPHOS-Rh		 100mg
500mg
2g
45-0171 (+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane
(cyclooctadiene)rhodium (I) trifluoromethanesulfonate,
98+%
(R,R)-Me-BPE-Rh		 100mg
500mg
2g
45-0170 (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane
(cyclooctadiene)rhodium (I) trifluoromethanesulfonate,
98+% (S,S)-Me-BPE-Rh
 100mg
500mg
2g
45-0205 1,1'-Bis(di-i-propylphosphino)ferrocene
(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate,
min. 98%		 250mg
1g
RUTHENIUM
44-0070 Bis(tricyclohexylphosphine)3-methyl-2-butenylidene ruthenium (IV) dichloride
 1g
5g
44-0080 Bis(tricyclopentylphosphine)3-methyl-2-butenylidene ruthenium (IV) dichloride 1g
5g
44-0210 Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium (II), min. 95%
 10mg
50mg
250mg
44-0211 Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium (II), min. 95% 10mg
50mg
250mg
44-0220 Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium (II), min. 98%
 10mg
50mg
250mg
44-0221 Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium (II), min. 98% 10mg
50mg
250mg
44-0222 Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium (II), min. 98% 10mg
50mg
250mg
44-0223 Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium (II), min. 98% 10mg
50mg
250mg
44-0248 Dichloro[(R)-(+)-2,2'-bis(diphenyl-phosphino)-1,1'- binaphthyl]ruthenium (II), min. 95% 500mg
2g
10g
44-7770 Tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene][benzylidine]ruthenium (IV) dichloride
SECOND GENERATION GRUBBS'S CATALYST
 500mg
2g